Spanning trees for the geometry and dynamics of compact polymers

Using a mapping of compact polymers on the Manhattan lattice to spanning trees, we calculate exactly the average number of bends at infinite temperature. We then find, in a high temperature approximation, the energy of the system as a function of bending rigidity and polymer elasticity. We identify the universal mechanism for the relaxation of compact polymers and then endow the model with physically motivated dynamics in the convenient framework of the trees. We find aging and domain coarsening after quenches in temperature. We explain the slow dynamics in terms of the geometrical interconnections between the energy and the dynamics.Comment: 10 pages, 8 figure

Removal of benzotriazole by Photo-Fenton like process using nano zero-valent iron: Response surface methodology with a Box-Behnken design

In this paper, the removal of benzotriazole (BTA) was investigated by a Photo-Fenton process using nano zero valent iron (NZVI) and optimization by response surface methodology based on Box-Behnken method. Effect of operating parameters affecting removal efficiency such as H2O2, NZVI, and BTA concentrations as well as pH was studied. All the experiments were performed in the presence of ultraviolet radiation. Predicted levels and BTA removal were found to be in good agreement with the experimental levels (R2 = 0. 9500). The optimal parameters were determined at 60 min reaction time, 15 mg L-1 BTA, 0.10 g L-1 NZVI, and 1.5 mmol L-1 H2O2 for Photo-Fenton-like reaction. NZVI was characterized using X-ray diffraction (XRD), transmission electron microscope (TEM) images, and scanning electron microscope (SEM) analysis

Heterogeneous oxidation of sulfacetamide in aquatic environment using ultrasonic and nano-fenton: Kinetics intermediates and bioassay test

In present study, degradation of sulfacetamide from a synthetic wastewater by sonofenton process using zero valent iron nanoparticles was investigated. The synthesized iron nanoparticles were characterized using transmission electron microscopy (TEM), UV-visible and X-ray diffraction pattern (XRD). The effect of various parameters, such as pH, nZVI dose, H2 O2 concentration and contact time was studied with batch experiments. The removal efficiency of sulfacetamide by US/nZVI/H2 Of process was about 91 for reaction time of 60 min, but less than 27 of chemical oxygen demand (COD) was removed. Kinetics studies showed that the degradation of sulfacetamide fitted well to the pseudo-second-order model. Using the LC/MS device, five intermediate from degradation of sulfacetamide were detected. The toxicity test, using micro toxicity study also showed that the effluent from the sono-Fenton reactor has a lower toxicity than sulfacetamide antibacterial. © 2019 Desalination Publications. All rights reserved